3-Methylpiperidinium bromide

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3-Methylpiperidinium ionic liquids.

A wide range of room temperature ionic liquids based on the 3-methylpiperdinium cation core were produced from 3-methylpiperidine, which is a derivative of DYTEK® A amine. First, reaction with 1-bromoalkanes or 1-bromoalkoxyalkanes generated the corresponding tertiary amines (Rmβpip, R = alkyl or alkoxyalkyl); further quaternisation reactions with the appropriate methylating agents yielded the ...

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In the cation of the title compound, C(7)H(7)N(2) (+)·Br(-), all non-H atoms are essentially coplanar [r.m.s. deviation = 0.010 (5) Å]. The compound is isomorphous with the chloride analogue. In the crystal, the cations and anions are connected by N-H⋯Br hydrogen bonds.

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The title compound, C(21)H(21)ClP(+)Br(-), is the bromide salt of a mixed aryl-alkyl phospho-nium cation. C-P-C angles span a range of 107.20 (10)-111.18 (10)°. The non-H atoms of the 3-chloro-propyl group adopt a staggered conformation [C-C-C-Cl torsion angle: -72.0 (3)°]. In the crystal, C-H⋯Br contacts connect the entities of the title compound into a double zigzag chain along b. These chain...

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In the title compound, C(13)H(23)N(2)O(2) (+)·Br(-), the octyl chain has an all-trans conformation. In the crystal, the cations are linked by C-H⋯O bonds into a zigzag chain along the b axis. The bromide anions further link the chains via C-H⋯Br inter-actions into a two-dimensional array parallel to the ab plane. An O-H⋯Br interaction is also observed.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s160053681201971x